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Free Full Version License Key Program For Activation.Electronic spectroscopic and computational studies of cation-π interactions of cationic imidazolium-based ionic liquids and transition metal cations.
The ionic liquids (ILs) are of great importance in the field of chemistry as they play a major role in fundamental studies, chemical processing, and many other applications. Moreover, cation-π interactions are being considered as a powerful tool in synthetic chemistry. Herein, we study the cation-π interactions of N-heterocyclic ionic liquids (NHI-ILs) and transition metal (TM) cations. The ionic liquids were synthesized using 1,3-dibromopropane and 1,4-bis(bromomethyl)benzene with various cationic units (1-hexyl-3-methylimidazolium, 1-hexyl-3-(dibenzylamino)imidazolium, 1-hexyl-3-(benzylamino)imidazolium, and 1-hexyl-3-(dibenzylamino)imidazolium bromide) and transition metal (Cu(II), Ag(I), Au(III), and Cd(II)) cations. The chemical structures of these ionic liquids were characterized by FT-IR, (1)H NMR, and elemental analyses. The spectroscopic analysis of the cation-π interaction was investigated by UV-vis and fluorescence spectroscopy. The data suggest that the presence 0b46394aab